Safety Data Sheet

Section 1Identification

1.1 Product identifier

Product form

Mixture

Trade name

Pave-Tech Tornado Crackfiller

Product code

13050

1.2 Relevant identified uses

Use of the mixture

Cold pour crack filler

1.3 Supplier

Pave-Tech
1283 Tri-County Hwy
Williamsburg, OH 45176
513.528.0777
www.tornadocrackfiller.com

1.4 Emergency telephone number

Emergency number

800-424-9300 CHEMTREC, 24 hours

Section 2Hazards Identification

2.1 Classification (GHS-US)

Carc. 1A

H350

STOT RE 1

H372

Full text of H-phrases: see Section 16.

2.2 Label elements (GHS-US)

Signal word: Danger

H350 – May cause cancer
H372 – Causes damage to organs through prolonged or repeated exposure

Precautionary statements (GHS-US)

• P201 – Obtain special instructions before use
• P202 – Do not handle until all safety precautions have been read and understood
• P260 – Do not breathe spray, vapours
• P264 – Wash hands, forearms and face thoroughly after handling
• P270 – Do not eat, drink or smoke when using this product
• P280 – Wear eye protection, protective clothing, protective gloves
• P308+P313 – If exposed or concerned: Get medical advice/attention
• P314 – Get medical advice/attention if you feel unwell
• P405 – Store locked up
• P501 – Dispose of contents/container in accordance with local, regional, and national regulations

2.3 Other hazards

No additional information available

2.4 Unknown acute toxicity (GHS-US)

Not applicable

Section 3Composition / Information on Ingredients

3.1 Substance

Not applicable

3.2 Mixture

Full text of H-phrases: see Section 16.

Section 4First Aid Measures

4.1 Description of first aid measures

General

IF exposed or concerned: Get medical advice/attention. Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible).

After inhalation

Remove person to fresh air and keep comfortable for breathing. Allow victim to breathe fresh air. Allow the victim to rest.

After skin contact

Wash skin with plenty of water. Take off contaminated clothing. If skin irritation or rash occurs: Get medical advice/attention. Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse.

After eye contact

Rinse eyes with water as a precaution. Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist.

After ingestion

Do NOT induce vomiting. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Obtain emergency medical attention.

4.2 Most important symptoms and effects, both acute and delayed

No additional information available

4.3 Immediate medical attention and special treatment

No additional information available

Section 5Firefighting Measures

5.1 Extinguishing media

Suitable

Carbon dioxide. Foam. Water. Dry chemical. Dry powder. Water spray. Sand.

Unsuitable

Do not use a heavy water stream.

5.2 Special hazards

Fire hazard

Not flammable in liquid state.

Explosion hazard

Product is not explosive.

Reactivity

Product is stable.

5.3 Advice for firefighters

Firefighting instructions

Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment.

Protection during firefighting

Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. Do not enter fire area without proper protective equipment, including respiratory protection.

Section 6Accidental Release Measures

6.1 Personal precautions, protective equipment and emergency procedures

General measures

Absorb spillage to prevent material damage.

Non-emergency personnel

Evacuate unnecessary personnel.

Emergency responders – protective equipment

Do not attempt to take action without suitable protective equipment. For further information refer to Section 8, “Exposure controls/personal protection.” Equip cleanup crew with proper protection.

Emergency responders – procedures

Ventilate area.

6.2 Environmental precautions

Avoid release to the environment. Prevent entry to sewers and public waters. Notify authorities if product enters sewers or public waters.

6.3 Methods and material for containment and cleaning up

Methods for cleaning up

Take up liquid spill into absorbent material. Soak up spills with inert solids, such as clay or diatomaceous earth, as soon as possible. Collect spillage. Store away from other materials. Notify authorities if product enters sewers or public waters.

Other information

Dispose of materials or solid residues at an authorized site.

6.4 Reference to other sections

For further information refer to Section 13. See Section 8, Exposure controls and personal protection.

Section 7Handling and Storage

7.1 Precautions for safe handling

Safe handling

Do not handle until all safety precautions have been read and understood. Obtain special instructions before use. Wear personal protective equipment. Avoid contact with skin and eyes. Do not breathe vapours. Ensure good ventilation; provide good ventilation in process area to prevent formation of vapour. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

Hygiene measures

Separate working clothes from town clothes. Launder separately. Do not eat, drink or smoke when using this product. Always wash hands thoroughly after handling the product.

7.2 Conditions for safe storage, including any incompatibilities

Storage conditions

Store locked up. Keep only in the original container in a cool, well-ventilated place away from heat sources. Keep container closed when not in use.

Incompatible products

Strong bases. Strong acids.

Incompatible materials

Avoid contact with strong oxidizers. Sources of ignition. Direct sunlight.

7.3 Specific end use(s)

No additional information available

Section 8Exposure Controls / Personal Protection

8.1 Control parameters

8.2 Exposure controls

Engineering controls

Ensure good ventilation.

Personal protective equipment

Gloves. Safety glasses. Avoid all unnecessary exposure.

Hand protection

Wear protective gloves.

Eye protection

Chemical goggles or safety glasses.

Skin and body protection

Wear suitable protective clothing.

Respiratory protection

Wear respiratory protection. Wear appropriate mask.

Environmental exposure controls

Avoid release to the environment.

Other information

Do not eat, drink or smoke during use.

Section 9Physical and Chemical Properties

9.1 Basic physical and chemical properties

Physical state

Liquid

Appearance

Black, thick liquid with a mastic-like consistency and a mild hydrocarbon odor

Colour

Black

Odour

Very mild hydrocarbon odor

Boiling point

≈ 212 °F

Density

≈ 1.05 g/cm³

Solubility (water), by component

Lithium hydroxide monohydrate: 22.3 g/100 ml · Xanthan gum: complete · Tall oil: 0.003 g/100 ml · Tetra-sodium pyrophosphate: 6 g/100 ml · Silica: insoluble · Titanium(IV) oxide: 0.15 g/100 ml · Methyl benzimidazol-2-ylcarbamate: 0.0008 g/100 ml · Kaolin: < 0.1 g/100 ml · 3-iodo-2-propynyl butylcarbamate: 0.02 g/100 ml

Odour threshold, pH, evaporation rate, melting/freezing point, flash point, auto-ignition and decomposition temperature, flammability, vapour pressure/density, relative density, Log Pow/Kow, viscosity, explosive/oxidising properties, explosive limits

No data available

9.2 Other information

No additional information available

Section 10Stability and Reactivity

10.1 Reactivity

Product is stable.

10.2 Chemical stability

Stable under normal conditions.

10.3 Possibility of hazardous reactions

Refer to 10.1 on Reactivity. Not established.

10.4 Conditions to avoid

Direct sunlight. Extremely high or low temperatures. See incompatible materials.

10.5 Incompatible materials

Oxidizing agents. Strong acids. Strong bases.

10.6 Hazardous decomposition products

Hydrogen sulfide, sulfides. Carbon dioxide. Carbon monoxide. Fume.

Section 11Toxicological Information

11.1 Information on toxicological effects

Acute toxicity

Not classified

Skin corrosion/irritation

Not classified

Serious eye damage/irritation

Not classified

Respiratory or skin sensitisation

Not classified

Germ cell mutagenicity

Not classified

Carcinogenicity

May cause cancer.

Reproductive toxicity

Not classified

STOT – single exposure

Not classified

STOT – repeated exposure

Causes damage to organs through prolonged or repeated exposure.

Aspiration hazard

Not classified

Potential adverse human health effects and symptoms

Based on available data, the classification criteria are not met.

Section 12Ecological Information

12.1 Toxicity

This product may cause adverse environmental effects if used improperly or released to the environment through a spill. Employ best management practices to prevent this material from entering storm sewer systems or waterways, or otherwise impacting plant and animal species.

12.2 Persistence and degradability

Not established.

12.3 Bioaccumulative potential

Not established.

12.4 Mobility in soil

No additional information available

12.5 Other adverse effects

No known ecological damage caused by this product. Avoid release to the environment.

Section 13Disposal Considerations

Waste treatment methods

This product, when discarded or disposed of, is not specifically listed as a hazardous waste in federal regulations. It could be designated as hazardous waste according to state regulations. This product could also become a hazardous waste if it is mixed with or comes in contact with a hazardous waste. If such contact occurs, consult 40 CFR to determine whether it is a hazardous waste.

Disposal recommendations

Dispose of contents/container in a safe manner in accordance with all local, state, and national regulations.

Ecology – waste materials

Avoid release to the environment.

Section 14Transport Information

DOT

Not regulated for transport. Not classified as a hazardous material under HM-181.

ADR

No additional information available

Transport by sea

No additional information available

Air transport

No additional information available

Section 15Regulatory Information

15.1 US Federal regulations

All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory except for:

This product or mixture does not contain a toxic chemical or chemicals in excess of the applicable de minimis concentration as specified in 40 CFR §372.38(a) subject to the reporting requirements of section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.

15.2 International regulations

Canada

No additional information available

EU regulations

No additional information available

Classification per Regulation (EC) No. 1272/2008 [CLP] / Directive 67/548/EEC or 1999/45/EC

Not classified

National regulations

Titanium(IV) oxide (13463-67-7) – Listed on IARC (International Agency for Research on Cancer)

15.3 US State regulations

California Proposition 65

This product does not contain any substances known to the state of California to cause cancer and/or reproductive harm.

New Jersey Right to Know Hazardous Substance List

Titanium(IV) oxide (13463-67-7); Asphaltic bitumen, not cut back (8052-42-4)

Section 16Other Information

Full text of H-phrases and classes

Hazard ratings

TBC SDS US (GHS HazCom 2012)